By Sivov

This quantity offers with chemistry of polyelectrolytes, particularly biocide guanidine containing polymers, discussing either synthesis of latest guanidine containing monomers of diallyl and acrylic nature and their constitution and research in their radical (co)polymerization and houses of latest (co)polymers. the 1st components of the ebook describe radical polymerization of those monomers and their co-polymerization with diallyldialkylammonium derivatives, gains in their kinetic habit in those procedures (for instance, polymerization charges, reactivity ratios) The sections on phycal chemical tools (IR, NMR, DSC ect.) are specifically very important for learning of constitution and homes of synthesized monomer and polymer compounds. The publication is finely illustrated with approximately hundred unique figures, schemes and tables together with kinetics, NMR, IR spectroscopy, biocide and different facts.

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On the base of said above it was obvious that the use of one fixed value of contraction under calculation of polymerization rates at various VP concentrations (measured by dilatometer method) led to incorrect calculations of V P on [VP] that gave anomalous results under determination of reaction order by monomer VP. A lot of works (for example [110]) are devoted to establishing of possible reasons of deviation of kinetic order regularities from "classic" standards in accordance with equation 2.

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